Chemistry
Revision for Structures exam
- Created by: Leigh Thomas
- Created on: 17-02-11 18:25
Atomic Structure:
Atomic mass = total protons & neutrons
Atomic Number = No of Protons
Proton Number = No of Electrons
Period No = No of Shells
Group No = No of e- in outer shell
Metal form compounds by loosing E`s, the larger the metal atom, the more easily the E.
Bonding
Metal + Metal = Metallic Bonding
Metal + Non Metal = Ionic Bonding
Non Metal + Non Metal = Covalent Bonding
Ionic Bond - Is the strong attraction between oppositely charged ions.
Metal Bond - All metal atoms lose their outer electrons and become positive ions
Covalent Bond - Between 2 non metal atoms involving sharing electrons
Metals always form Positive Ions (Cations attracted to the cathode)
Non Metals always form negative ions ( Anions attracted to the anode)
Electrolysis
To conduct electricity we need charged particals ( electons and ions) which are free to move
Positive ions move to the negative electrode, gaining a number of electrons
negative ions move to the posstive electrode, loosing a number of electons
The metal ions are arrange in a giant lattice, surrounded by a sea of electrons
simple covalent compounds have low melting points because the force between the particles is weak and only needs a small amount of energy to separate them
Crude Oils
Pertrol
Naptha
Kerosene
Diesel
Oils
Bitumein + wax
Cracking
Cracking involves the breaking down of long chain hydrocarbons into more usefull shot chain hydrocarbons which release energy more qucikly when burned.
Alkane are saturated hydrocarbons containing only one single bond
CnH2n+ 2
Alkenes are unsaturated hydrocarbons contains at least one double bond
CnH2n
Cracking producses 3 mollecules of ethene and one other product.
Alkenes
Test for alkenes
Bromine water is decolourised by alkenes ( Orange to colorless)
Polymer - Very long chains of hydrocarbons, used as plactics made by linking lots of alkene molucules together
addition polymers - made from alkenes - Thermosetting & Thermoplastic
Thermosetting - Rigid, reatins shape can not be re- molded or re-shaped
Thermoplastic - can be melted and then re molded into a different shape.
Collision Theory
For any reaction to occur, particles must collide. the particles must have sufficient energy - activation energy
anythink that:
1) cause more collisions
2) increases energy of particles
3) reduces activity energy
will speed up the rate of reaction
Particles have move energy causing the particles to cover a wide surface area in the same time more likely to cause collisions
Catalyst
catalyst is something that speeds up the rate of reaction or takes part in the process to create a faster solution without being used up
e.g Yeast for alcohol, magnesium ox-side for aluminum
catalyst are extremely important in industry e.g catalyst in cars.
the smaller the particle size, results in a bigger surface area as it is also equivalent of mass meaning move collisions and faster reactions
Relative Molecular Mass
RMM = sum of atomic masses of all atoms in a compound
H20 = 2xH (2x1) + 1xO (1x16) = 18
% element in a compound
Atomic Mass of Elements x No of Atoms X 100
Molecular Mass of Compound
Relative Molecular Mass
% of Atom Economy - Higher Yield Less Waste, Lower Yield More Waste
Mass or Usefull Product X100
Total Mass of all Products
Reacting Masses
How Much Magnesium will react with 50G of Oxygen
What mass of sulfur is need to make 500g of H2S4
% of Yield
mass of product x 100
maximum possible mass
100g of magnesium product produced 116g of mgo what is the % yield
264g of silver chloride was orbtained from the reaction of magnesium chloride and silver nitrate (ag=108 cl = 35.5)
Empirical Formula
Simplest Ratio Of atoms in a molecule
eg ethene has formulas c2h4 emprical = c2
c3h8 emprical = same
c6h14 emprical = c3h7
a compound of carbon and oxygen contains 0.30g c and 0.80G of o
Emprical Formulma
A compound contains 20% magnesium 26.1% sulfur and rest = oxygen
find the emprical formula
Equilibrium
Equilibrium - the rate of the forwards and backwards reactions is the same
in a system at eqilibrium the postion of equilibrium will move to oppose changles to the conditions
Harber Process
Endo & Exo
Bond Breaking is Endothemric
Brond Making is Exothermic
the reaction is extothermic beacuse there is a stronger bong causing more energy creating more heat
endothermic beaxcuse it takes move energy needed to break a bond.
fertilisers
Fertilsers
mainly contain nitrogen; phosphorus aqnd potassium
advatages- no need for crop rotations
Larger Crops
More effective use
Disadvatges - soluable
eutrophication
cracking diagram
Force Between Particels
melting points depends on how strongly particles are attracted to each other. melting required particles to be free to move - i.e overcomes forces of attraction
electrons & ions must be free for any atom to conduct electricity
chemical bonds are strong - covalent , ionic, metallic
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